Name | Manganese [II] acetate, tetrahydrate |
Synonyms | MANGANESE(II) ACETATE Manganese acetate hydrate Manganese acetate tetrahydrate MANGANOUS ACETATE TETRAHYDRATE Manganese(Ⅱ) acetate tetrahydrate Manganese ii acetate, tetrahydrate Manganese(Ii) Acetate Tetrahydrate Manganese [II] acetate, tetrahydrate Acetic acid,Manganese(2+) salt, tetrahydrate (8CI,9CI) |
CAS | 6156-78-1 |
EINECS | 612-176-1 |
InChI | InChI=1/C2H4O2.Mn.4H2O/c1-2(3)4;;;;;/h1H3,(H,3,4);;4*1H2/q;+2;;;;/p-1 |
InChIKey | SLMRUTJYVMZEPJ-UHFFFAOYSA-M |
Molecular Formula | C4H14MnO8 |
Molar Mass | 245.09 |
Density | 1.589g/mLat 25°C(lit.) |
Melting Point | >300°C(lit.) |
Water Solubility | Soluble in water, methanol, ethanol, and acetic acid. |
Solubility | 233g/l |
Vapor Presure | <1 hPa (25 °C) |
Appearance | Bright red crystal |
Specific Gravity | 1.589 |
Color | Pink |
Exposure Limit | OSHA: Ceiling 5 mg/m3NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3 |
Merck | 14,5724 |
BRN | 3730728 |
PH | 7.0 (50g/l, H2O, 20℃) |
Storage Condition | Store below +30°C. |
Sensitive | 4: no reaction with water under neutral conditions |
MDL | MFCD00062552 |
Physical and Chemical Properties | Light red crystal. |
Use | Used as oxidation catalyst and paint drier |
Hazard Symbols | Xi - Irritant |
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. |
WGK Germany | 2 |
RTECS | AI5775000 |
TSCA | Yes |
HS Code | 29152990 |
Toxicity | LD50 orally in Rabbit: 3730 mg/kg |
Raw Materials | Acetic acid Manganese |
light red crystals. Relative density 11 59. Melting point 80 °c. Very soluble in water and ethanol.
The metal manganese is reacted with acetic acid by heating, and the reaction product is adjusted to pH with hydrogen peroxide, and then subjected to distillation, concentration, crystallization and dehydration. Or manganese sulfate and soda ash heating reaction, the formation of manganese carbonate, and acetic acid reaction, the reaction product by filtration, concentration, crystallization, dehydration.
The catalyst used in transesterification reaction is about 0.01% ~ 0. o5% in polyester resin production. It can also be used as an Acetaldehyde Oxidation Catalyst, a xylene high temperature oxidation catalyst, a fiber dyeing oxidation catalyst, a mordant, a drying agent for coatings and paints. Also used as fertilizer, food and feed additives.
rat oral LD50;3.73g/kg.
purpose | used as oxidation catalyst and paint drier The product is a catalyst for high temperature oxidation of xylene, a raw material of polyester resin. It can also be used as a mordant for dyeing, a desiccant for paints and varnishes, and a catalyst for oxidation processes. |
production method | is obtained by reacting manganese with acetic acid. The metal manganese was soaked with 5% acid elimination for 5min, rinsed several times with distilled water until the pH value was 8. Then, acetic acid is added to carry out the synthesis reaction, and the crude manganese acetate is first prepared, and a small amount of activated carbon is added to remove metal ions such as iron and lead. The filtrate was then filtered, adjusted to pH 3-4 with acetic acid (chemically pure), evaporated to a relative density of 1.30, and cooled, crystallized, centrifuged, and dried (below 50 ° C.) to obtain a finished product. Raw material consumption (kg/t) acid (industrial) 1100 manganese metal (industrial) 380 nitric acid (industrial) 10 |
category | toxic substances |
toxicity grade | poisoning |
Acute toxicity | oral-rat LD50: 3730 mg/kg |
flammability hazard characteristics | |
storage and transportation characteristics | warehouse low temperature, ventilation, dry |
extinguishing agent | water, carbon dioxide, dry powder, sand |
Occupational Standard | TWA 5 mg/m3 |